No. There is 4 extra slots for the whole of europe.
2 of which are for clubs that fall outside of automatic qualifying positions. So they could be in the Europa league for instance.
‘Awarded to the two clubs with the highest club coefficients that have not qualified automatically for the Champions League’s league stage, but have qualified either for the Champions League qualification phase or the Europa League/the Europa Conference League (due to start in the 2021/22 season).’
it’s designed purely for when one of the 12 have bad seasons a la Liverpool, Spurs and arsenal this season.