Staying in Phoenix for work for 4 days then have 3-4 days on the bikes between Phoenix, Kingman, Sedona and Page
Escaping Phoenix will suck, it's huge, but once you finally break free Northern Arizona is pretty scenic, some good views. As for itself, i guess any advice I might offer depends entirely upon where in the city you are staying. Not shocking to spend an hour going door to door to see my friends... and not because of slow traffic, we're talking 55+mph on freeways.
Kingman is about an hour east of Bullhead, some mountains there, so might get "cold" for Arizona.
Sedona... stayed about a week in Sedona and Oak Creek for our Honeymoon. Struggling to think of the places we ate at there, though rated low on Google, I remember enjoying a great huevos rancheros breakfast at Oaxaca and they had an ok microbrew in some weird fancy pants shopping center.
If you can squeeze Prescott in, I really liked the town center. Olde Tyme feel, copper ceiling work, etc, on some of the bars on Whiskey Row. It sort of fits in that general loop, i think.